first thing first: you do realize that these two instruments are completely different, right? while psr is an arranger, triton le gives you at most some programs that contain percution, bass, etc. but quite unadjustable for use as backing tracks (as psr offers you).
programs are sounds. combi is a combination of different sounds (programs) sometimes togheter with some arpeggios, so it sounds almost as a full orchestration. (it is not, tho).
for the other questions, the only way to understand exactly is to spend good time with the manual. i am sure it is explained how to use effects and stuff.
finally, triton le is a synth. psr xyz is an arranger. they are meand for different use.
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