There are two things that can cause an alkaline battery to do this--excessive heat, and a short circuit. I experienced the same thing, and like you I also carry spare batteries in my gig bag. However, I now tape a small piece of cardboard over the terminals to prevent shorts. Last summer, I opened the bag to get out a fresh battery and it was red hot. The terminals had been in contact with a small screwdriver that was also in the same compartment which caused a dead short. Not only was the battery red hot, so was the screwdriver, and the battery was bulging out the bottom--bad news. Fortunately, I had another spare in the bag that was OK and was able to get through the night on it.
Gary
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PSR-S950, TC Helicon Harmony-M, Digitech VR, Samson Q7, Sennheiser E855, Custom Console, and lots of other silly stuff!
K+E=W (Knowledge Plus Experience = Wisdom.)